Some inorganic nanostructure materials with high light absorption

Some inorganic nanostructure materials with high light absorption of the visible spectrum and the near infrared spectral range are dispersed in to the polymer:fulleride layer to increase the light absorption such as CdS [14, 15], CdSe [16], PbS [17], Sb2S3[18], and FeS2[19, 20]. In addition, some inorganic materials with high charge carrier mobility, such as ZnO and TiO2, are used to increase the charge find more transport efficiency and reduce the charge recombination [21–23]. Specially, because the ordered TiO2 nanotube

arrays (TNTs) possess outstanding charge transport properties, the TNTs are used to reduce the charge recombination in the PSCs and therefore improved the efficiency as reported recently [24]. It

is worthy to note that most of these materials are synthesized in advance through complicated chemical method and then dispersed in active layers. Of which, usually, MAPK Inhibitor Library order only one type of these inorganic nanostructure materials is dispersed in active layer. However, there are few reports on which two types of inorganic nanostructure materials are compactly combined and dispersed in active layers. This report selleck chemicals focuses on the synthesis of the CdS quantum dot (QD)-sensitized TiO2 nanotube arrays (CdS/TNTs) in a simple way (chemical bath deposition (CBD)) and dispersion in active layers. CdS QDs help light absorption to produce more excitons and also help to form the interface of CdS/P3HT with P3HT in the P3HT:PCBM layer so that more excitons are separated. TNTs are able to make prompt transfer of the excitons produced by light absorption of CdS QDs. Excitons are separated efficiently enough to reduce Progesterone the charge recombination. Meanwhile, TNTs are used to form the interface of

TNTs/P3HT with P3HT in the active layer and also enhance the separation of excitons. Therefore, CdS/TNTs synthesized using the CBD method and dispersed in P3HT:PCBM layer not only increase the light absorption but also reduce the charge recombination. It is known that few studies on the synthesis of CdS/TNTs using the CBD method to enhance PSCs’ PCE are reported. The result shows that after the CdS/TNTs are dispersed in the P3HT:PCBM layer, the light absorption of the active layer is greatly improved, and the charge recombination is largely controlled. Comparing to the device without CdS/TNTs, the efficiency of the device with CdS/TNTs mentioned above increases by 34%, which fully proves the reasonability of this reported method. Methods Fabrication of TNTs Highly ordered and vertically oriented TNTs were prepared by anodization of Ti (titanium foil, 0.25-mm thickness, 99.7% purity; Sigma-Aldrich, St. Louis, MO, USA) sheets in an electrolyte consisting of 0.25 wt.% ammonium fluoride (NH4F) (98 + % purity; Sigma-Aldrich) and 0.5 wt.% distilled (DI) water in ethylene glycol (EG) (C2H6O2, 99.0% purity; Sigma-Aldrich) at 40 V for 8 h.

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