6 h for glycerol and 13.1 h for sorbitol). The films plasticized with glycerol ( Fig. 1a) require longer drying time than the films plasticized with sorbitol ( Fig. 1b), for the same drying conditions. This is because glycerol acts as a water holding agent,

while sorbitol functions as plasticizer with minimum contribution from water molecules ( Tapia-Blácido et al., 2011). According to the variance analysis (ANOVA), the models calculated for the tensile strength (TS), elongation at break (E), and Young’s modulus (YM) of flour films plasticized with glycerol (equations (6), (7) and (8)) and sorbitol (equations (9), (10) and (11)) are statistically significant (p < 0.05) and predictive (Fcal > Flist). For ITF2357 price glycerol: equation(6) TS=4.47+0.14X1−0.98X12+0.30X22−0.68X1X2(R2=0.90) equation(7) E=26.47+7.58X12−6.78X22+6.89X1X2(R2=0.87) equation(8) YM=228.66−65.45X12−15.09X2−53.19X1X2(R2=0.88) http://www.selleckchem.com/products/chir-99021-ct99021-hcl.html For sorbitol: equation(9) TS=6.59−0.52X2−1.49X1X2(R2=0.90) equation(10) E=20.48−2.53X12−3.49X22+3.50X1X2(R2=0.88) equation(11) YM=306.61+23.44X1−36.35X2+49.30X12−10.98X22−80.68X1X2(R2=0.91) Fig. 2 corresponds to the response surface of TS of the films plasticized with glycerol or sorbitol as a function of T (X1) and RH (X2). Fig. 2a shows that higher TS values are achieved at lower drying rate (30 °C, 76% RH). Moreover, lower TS values

had been attained at an intermediate drying rate (26 °C, 34% RH or 54 °C, 76% RH). These results contrast with data obtained for flour films from the species A. caudatus plasticized with glycerol because the latter films, which were dried at 50 °C and 70% RH, were more resistant Dimethyl sulfoxide to strain ( Tapia-Blácido et al., 2005b). Concerning the film plasticized with sorbitol, the effect

of T on the TS values is only evident at low RH ( Fig. 2b). In these films, the TS values are mainly affected by the RH. In addition, the films plasticized with sorbitol and dried at higher drying rate (54 °C, 34% RH) furnish a larger TS value (∼10 MPa). The effect of T and RH on the elongation at break (E) has inverse behavior compared with the TS ( Fig. 3). As usual, more resistant films are less ductile. The E response surface of flour films plasticized with sorbitol display a maximum region defined at intermediate T and RH values ( Fig. 3b). Hence, flour films dried at T between 30 and 45 °C and RH ranging from 45 to 60% result in more flexible films (E ∼ 21%). On the other hand, the flour films plasticized with glycerol give higher E values when they are dried at higher T (54 °C) and RH (70–76% RH), compared with the flour film plasticized with sorbitol. In the case of the flour film from the species A. caudatus plasticized with glycerol ( Tapia-Blácido et al., 2005b), larger E values have been reported for films dried at lower drying rate (30 °C and 70% RH).