X-ray photoemission spectroscopy (XPS) has been conducted on the H(2)O(2) treated ZnO surface. The surface exhibits high resistive conductivity after the H(2)O(2) treatment, suggesting that the treatment promotes selleckchem a compensation effect. We demonstrate that dramatic improvement in the rectifying behavior on the Schottky diodes can be achieved by inserting a ZnO(2) interface layer between the Pt Schottky electrode and the ZnO nano-column film. The ZnO(2) interface layer promotes surface passivation and suppresses the surface leakage current. This is expected to increase the Schottky barrier height to 0.78 eV. The H(2)O(2)
treated Schottky diode showed five orders of magnitude in current rectification between forward and reverse bias at 3 V. (C) 2011 American Institute of Physics. [doi:10.1063/1.3582143]“
“We demonstrate nano-scale optical analysis of graphene layers by tip-enhanced near-field Raman spectroscopy (TERS). In this technique, the spatial resolution similar to 30 nm is realized by the near-field probe which acts as a nano-light Navitoclax datasheet source. From the intensity change of the Raman band of silicon generated from the near-field probe, we can conveniently estimate the edge boundaries and the number of stacking
layers. TIERS measurement across the layer edges reveals the nano-scale properties of the material as well as the existence of local defects and edge boundaries. The intensity change of the G-band shows the step-like behavior that follows the layer boundary, whereas the two components in 2D peak show more complex behaviors even inside layers. The peak fluctuation in the 2D band
also suggests the local stress distribution due to interlayer interactions. An excess charge effect is observed through the correlation between the peak position and the width of the G-band and their nano-scale distribution within a layer is revealed. Besides the vibrational SHP099 analysis, we successfully performed the estimation of the number of layers in two-dimensional imaging by the same experimental platform, which allows us high-throughput nondestructive identification of graphene layers critical for the evaluation of this material especially in future device applications. Copyright (C) 2009 John Wiley & Sons, Ltd.”
“Field observations, isolations and pathogenicity tests were performed on Austrocedrus chilensis (Cupressaceae) trees to determine the pathogenicity of Phytophthora austrocedrae and its role in the aetiology of the cypress disease mal del cipres (MDC) in Argentina. It was found that P. austrocedrae is a primary pathogen of A. chilensis. It was isolated from large necrotic lesions in the inner bark, and superficially in the sapwood, at the root collar and stem, in most of the MDC-affected stands surveyed along the range of A. chilensis in Argentina.